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マトリックス効果の疑われる農薬リスト

農薬の分類:P:有機リン系,PY:ピレスロイド系,CA:カルバメート系;TR:トリアジン系;N:CA,TR以外の含窒素系;回収率は目安として示した.1つの文献中で複数の条件が述べられている場合,最もマトリックス効果の大きい例について記載した.参考文献は別ファイルに示した.

No.

pesticide

class

products

detector

column

recovery

referance

note

1

3-hydroxycarbofuran

CA

foods

FTD,NPD

OV-210+OV-17

 

2

metabolite of carbofuran

2

acephate

P

butterfat

FPD(P)

DB-17

120

6

 

3

acephate

P

milk

FPD(P)

DB-17

154

6

 

4

bitertanol

N

spinach

MS

DB-5

128.1

1

 

5

captafol

N

brown rice

FPD(S)

CBP-1

33.9

7

 

6

captafol

N

chestnut

FPD(S)

CBP-1

ND

7

 

7

captafol

N

cucumber

FPD(S)

CBP-1

7.9

7

 

8

captan

N

brown rice

FPD(S)

CBP-1

60.0

7

 

9

captan

N

chestnut

FPD(S)

CBP-1

25.5

7

 

10

captan

N

cucumber

FPD(S)

CBP-1

21.1

7

 

11

carbofuran

CA

foods

FTD,NPD

OV-210

 

2

 

12

chlornitrofen

N

brown rice

MS

DB-5

126.6

1

 

13

chlornitrofen

N

spinach

MS

DB-5

131.3

1

 

14

chloropyrifos

P

tap water

MS

Ultra-2

130

4

 

15

chlorpyrifos

P

butterfat

FPD(P)

DB-17

116

6

 

16

chlorpyrifos

P

milk

FPD(P)

DB-17

131

6

 

17

chlorpyrifoxon

P

tap water

MS

Ultra-2

480

4

chlorpyrifos metabolite

18

cyfluthrin

PY

lemon

MS

DB-5

121.8

1

 

19

cyfluthrin

PY

spinach

MS

DB-5

134.3

1

 

20

cylahothrin

PY

spinach

MS

DB-5

123.6

1

 

21

cypermethrin

PY

lemon

MS

DB-5

126.9

1

 

22

cypermethrin

PY

spinach

MS

DB-5

124.4

1

 

23

DEF

P

legumes

FPD(P)

OV-101

126

8

 

24

diazinon

P

butterfat

FPD(P)

DB-17

114

6

 

25

diazinon

P

milk

FPD(P)

DB-17

135

6

 

26

dimethoate

P

butterfat

FPD(P)

DB-17

116

6

 

27

dimethoate

P

leafy vegetables

FPD(P)

OV-101

180

8

 

28

dimethoate

P

milk

FPD(P)

DB-17

129

6

 

29

diphenyl

others

lemon

MS

DB-5

131.7

1

 

30

edifenphos

P

spinach

MS

DB-5

123.8

1

 

31

EPN

P

spinach

MS

DB-5

139.5

1

 

32

ethion

P

legumes

FPD(P)

OV-101

133

8

 

33

ethion

P

potatoes

FPD(P)

OV-101

125

8

 

34

fenitrothion

P

tap water

MS

Ultra-2

284

4

 

35

fensulfothion

P

spinach

MS

DB-5

129.3

1

 

36

fenthion

P

tap water

MS

Ultra-2

147

4

 

37

flucythrinate

PY

spinach

MS

DB-5

124.3

1

 

38

flutolanil

N

spinach

MS

DB-5

135.6

1

 

39

fluvalinate

PY

lemon

MS

DB-5

136

1

 

40

fluvalinate

PY

spinach

MS

DB-5

128.5

1

 

41

folpet

N

brown rice

FPD(S)

CBP-1

64.8

7

 

42

folpet

N

chestnut

FPD(S)

CBP-1

28.5

7

 

43

folpet

N

cucumber

FPD(S)

CBP-1

16.9

7

 

44

iprodione

N

foods

FTD,NPD

OV-17

 

2

 

45

isofenphos

P

tap water

MS

Ultra-2

147

4

 

46

isofenphoxon

P

tap water

MS

Ultra-2

134

4

isofenphos metabolite

47

isoxaoxon

P

tap water

MS

Ultra-2

127

4

isoxathion metabolite

48

isoxathion

P

spinach

MS

DB-5

127.8

1

 

49

malaoxon

P

tap water

MS

Ultra-2

348

4

malathion metabolite

50

malathion

P

tap water

MS

Ultra-2

166

4

 

51

mefenacet

N

spinach

MS

DB-5

121.7

1

 

52

metalaxyl

N

foods

FTD,NPD

OV-17

 

2

 

53

methamidophos

P

butterfat

FPD(P)

DB-17

93

6

 

54

methamidophos

P

milk

FPD(P)

DB-17

165

6

 

55

methomyl oxyme

CA

foods

FPD(S)

FFAP

 

2

derivative of methomyl

56

metribuzin

N

brown rice

NPD

DB-210

123

3

 

57

N-(3,5-dichlorophenyl) -3-isopropyl-2,4- dioxoimidazolidine -1-carboxamide

N

foods

FTD,NPD

OV-17

 

2

metabolite of iprodione

58

omethoate

P

butterfat

FPD(P)

DB-17

123

6

 

59

omethoate

P

milk

FPD(P)

DB-17

152

6

 

60

oxamyl oxyme

CA

foods

FTD,NPD

XE-60

 

2

metabolite of oxamyl

61

permethrin

PY

brown rice

MS

DB-5

120.4

1

 

62

phenthoate

P

tap water

MS

Ultra-2

157

4

 

63

phenthoxon

P

tap water

MS

Ultra-2

264

4

phenthoate metabolite

64

phosalone

P

brown rice

MS

DB-5

122

1

 

65

phosalone

P

spinach

MS

DB-5

122.3

1

 

66

phosmet

P

spinach

MS

DB-5

122.2

1

 

67

piperophos

P

tap water

MS

Ultra-2

62

4

 

68

piperophoxon

P

tap water

MS

Ultra-2

205

4

piperophos metabolite

69

propaphos

P

tap water

MS

Ultra-2

164

4

 

70

propaphos sulfone

P

tap water

MS

Ultra-2

194

4

propaphos metabolite

71

prothiofos

P

tap water

MS

Ultra-2

174

4

 

72

prothiofoxon

P

tap water

MS

Ultra-2

148

4

prothiofos metabolite

73

pyrazoxyfen

N

lemon

MS

DB-5

131.6

1

 

74

pyrethrins

PY

brown rice

MS

DB-5

127

1

 

75

pyrethrins

PY

brown rice

ECD

DB-1

128

3

 

76

pyrethrins

PY

lemon

MS

DB-5

127.2

1

 

77

pyrethrins

PY

spinach

MS

DB-5

150.1

1

 

78

pyridaben

N

brown rice

MS

DB-5

121.5

1

 

79

pyridaben

N

spinach

MS

DB-5

121.9

1

 

80

pyridaphenoxon

P

tap water

MS

Ultra-2

750

4

pyridaphenthion metabolite

81

pyridaphenthion

P

tap water

MS

Ultra-2

159

4

 

82

simetryne

TR

tap water

MS

Ultra-2

150

4

 

83

sulprofos oxon sulfone

P

foods

FTD,FPD(P),NPD

SE-30

 

2

sulprofos metabolite

84

sulprofos sulfone

P

foods

FTD,FPD(P),NPD

SE-30

 

2

sulprofos metabolite

85

tetrahydrophthalimide

N

milk

MS

DB-17

 

9

captan, captafol metabolite

86

thiometon sulfone

P

foods

FTD,FPD(P),NPD

OV-17

 

2

thiometon metabolite

87

tolclofoxon-methyl

P

tap water

MS

Ultra-2

249

4

tolclofos-methyl metabolite

88

triadimenol

N

brown rice

MS

DB-5

147.5

1

 

89

triadimenol

N

spinach

MS

DB-5

138.3

1

 

90

trichlamide

N

spinach

MS

DB-5

122.1

1

 

91

tricyclazole

N

foods

FTD,NPD

PEG20M

 

2

 

92

tricyclazole

N

brown rice

FTD

DB-1

 

10

 


更新日 98/04/16
名前 津村ゆかり